Don't do it.
There is a fine line in terms of usability - on one hand sometimes I may have intended to place an order but accidentally left the page; on the other hand it could get annoying pretty quickly. When abrowser is set up to save previous session (i.e. reopen tabs on next launch) and one page behaves this way, you'll end up with only that tab re-opened next time (confirmed on Mac Safari), discarding the rest of the tabs. They'll not be buying from you again!
I'd suggest you make it clear to the user by means of inline messages that the order has not been submitted yet and they still need to confirm their action, but if they were to accidentally navigate away you should make it easy to pick up where they left off. Would be fairly trivial to store such info in a cookie so that on subsequent page visits the user would be prompted with "you have an incomplete order for ..., would you like to finish it now?"
As an alternative, you could use rely on an inactivity alert (think of online banking prompting you when your session is about to expire) to bring the user back to the "complete order" page if they get distracted.
If you are certain you want to rely on this event, the answers to this question may provide better insight. Basically, the functionality or its implementation beyond a basic text warning should not be relied onto because of inconsistent (?) implementation across browsers as well as possibility of having it blocked by the user.
Prompted by Derek's comment on this approach being used by Gmail etc., I've come across an article suggesting you stick with
I'm looking to implement a warning if the user attempts to leave the order process before it's completed in any fashion other then of course following the payment button.
Something like this:
I'm sure that's detrimentally wrong in a few ways, but it's the best way I can illustrate what I'm trying. And I understand some browsers will display default text instead of the actual warning I've written, that's fine.
A few notes, I'd rather use plain old JS instead of loading up jQuery for just this one simple task. There are no settings on the page so it's a simple leave page or click "Buy Now" operation.
I assure you it's not for my sake, it's for the user's sake. Although it's explicitly explained (what to do), I think user's are jumping the gun and leaving before the process is truly finished out of an instant gratification, ignore the messages kind of mentality. It's a simple 2-step process, they submit the details for the project and then make payment. For whatever reason they're submitting details and then not following through with payment about 50% of the time. And then they'll follow up "So, are you working on the project or what?" and then I have to explain "You never finished your order." They follow up with a "Whoops, here ya go."
Unfortunately, I would chalk this up as marketing and web design 101. Rule #1, people are dumb. Not to be taken in a rude or pessimistic sense. Basically, the idea is assume everyone is dumb in your design, instruction so that you make something so easy a five-year-old can do it. I totally agree with not holding users hostage. But this page is ONLY reached in the middle of their intended order process that THEY initiate (this page will never be reached in a browsing sort of way). So I think it's a pretty legitimate use case where you're saving a common user mistake from themselves. A demographic of customers that are not tech-savvy, so they honestly need such guidance.